| Autor: |
Rogers, J. R., Downey, J. P., Witherow, W. K., Facemire, B. R., Frazier, D. O., Fradkov, V. E., Mani, S. S., Glicksman, M. E. |
| Zdroj: |
Journal of Electronic Materials; October 1994, Vol. 23 Issue: 10 p999-1006, 8p |
| Abstrakt: |
An experimental study of diffusional coarsening, or Ostwald ripening, in a liquid-liquid two-phase system is described. An experiment performed at its isopycnic point, 42°C, allowed observations for the long times required to investigate coarsening. A holographic technique was instrumental in this work. Holograms takenin situpermit investigation of details regarding both the influence of local environmental conditions on individual droplet size histories and measurement of global averages. This study utilized a 100 μm pathlength test cell. The discrete phase was nucleated on one wall of the cell. This configuration resembles island formation in thin film growth. Observation of Ostwald ripening over a period of 1×107s (∼4 mo.) reveals that droplet number decays as t−0.733and the average radius increases as t−0.247, in the asymptotic limit. This shows good agreement with theoretical predictions for diffusional growth of spherical caps on a two-dimensional substrate which is a valid approximation for the geometry of this experiment. Part I of this paper describes the experimental results. Part II discusses a numerical model for droplet growth in a comparison with the experimental results. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
Full text from SpringerLink