Cyclometallation, part II. I.r. and1H N.m.r. studies of palladium(II) compounds with substitutedN-(benzylidene)amines

Autor:	Vila, José M., Pereira, María T., Gayoso, Eduardo, Gayoso, Miguel
Zdroj:	Transition Metal Chemistry; September 1986, Vol. 11 Issue: 9 p342-346, 5p
Abstrakt:	New cyclometallated complexes of palladium containing substitutedN-(benzylidene)amines have been prepared and characterized. Palladium(II) acetate is used to make the acetato-bridged dimers, which undergo metathetical reactions to give the halo-bridged dimers. These when treated with PPh3 or P(C6H11)3 in a 1:2 molar ratio yield the phosphine monomers. I.r. and1H n.m.r. studies show that palladium is coordinated through nitrogen, and also reveal the disposition of the halogen and phosphine ligands in the monomeric complexes.
Databáze:	Supplemental Index
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