| Autor: |
Halawani, Kamal H., Mostafa, Ahmed H. |
| Zdroj: |
Transition Metal Chemistry; December 1993, Vol. 18 Issue: 6 p564-566, 3p |
| Abstrakt: |
[MCl2L4] complexes (M = Co or Ni; L = 3-hydroxypyridine) were prepared by the reaction of stoichiometric amounts of 3-hydroxypyridine and MCl2 in EtOH solution. The complexes were chlorinated by passing Cl2 gas through EtOH solutions containing the metal(II) chloride and 3-hydroxypyridine to yield [CoCl2(LCl)2]·2H2O and [NiCl2(LCl)4]·4H2O, respectively. Structural assignments have been inferred from elemental and spectral analyses. Magnetic properties of the complexes are assigned and the electronic transitions are discussed. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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