| Autor: |
Li-Kao, Julia, Bustos, Carlos, Carrillo, David, Robert, Francis, Gouzerh, Pierre |
| Zdroj: |
Transition Metal Chemistry; June 1993, Vol. 18 Issue: 3 p265-270, 6p |
| Abstrakt: |
[MoO2(acac)2] reacts with two equivalents of arylhydrazines in MeOH or MeCN to give mononuclear bis(aryldiazenido) molybdenum complexes of the type [Mo-(NNC6H4R-p)2(acac)2], where R = H (1); Me (2); MeO (3); F (4) or NO2 (5). These complexes have been characterized by i.r., 1H-n.m.r. and u.v.-vis. spectroscopy. The crystal structures of (2) and (3) have been determined. Both lattices are made of discrete mononuclear species containing the cis-[Mo(NNAr)2]2+ unit with singly bent aryldiazenido ligands. |
| Databáze: |
Supplemental Index |
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