Ammonium and potassium fluoromonooxalatomanganates(II), A[MnF(C2O4)] (A = NH4 or K) and sodium fluoromonooxalatomanganate(II) dihydrate, Na[MnF(C2O4)] · 2H2O

Autor: Bhattacharjee, Manabendra N., Chaudhuri, Mihir K.
Zdroj: Transition Metal Chemistry; May 1986, Vol. 11 Issue: 5 p193-195, 3p
Abstrakt: Summary Light pink-white microcrystalline ammonium and potassium fluoromonooxalatomanganates(II), A[MnF(C2O4)] (A = NH4 or K), and sodium fluoromonooxalatomanganate(II) dihydrate, Na[MnF(C2O4)] · 2H2O, have been synthesized by two different methods. Either KMnO4 is reduced in the presence of 40% HF and alkali metal oxalate, A2C2O4 (A = NH4, Na or K), or MnO(OH) in 40% HF reacts with A2C2O4. Characterisation was made by elemental analyses, determination of oxidation states, magnetic susceptibility measurements and infrared spectral studies.
Databáze: Supplemental Index
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