Synthesis, protonation and substitution behaviour of K3[ReO2(CN)4]

Autor: Leipoldt, Johann G., Basson, Stephen S., Roodt, Andreas, Purcell, Walter
Zdroj: Transition Metal Chemistry; June 1987, Vol. 12 Issue: 3 p209-212, 4p
Abstrakt: Summary The preparation and characterization of salts of the [ReO2(CN)4]3-, [ReO(OH)(CN)4]2-, [ReO(H2O)(CN)4]-, [Re2O3(CN)8]4- and [ReO(NCS)(CN)4]2- species are described. The nature of the protonation reactions of [ReO2(CN)4]3- was established by the successful isolation of these salts.
Databáze: Supplemental Index