Calorimetric determination of the heats of formation of lanthanide monosulfate complexes in D2O1

Autor: Farrow, Michael M., Purdie, Neil, White, Wesley D.
Zdroj: Journal of Solution Chemistry; May 1974, Vol. 3 Issue: 5 p395-401, 7p
Abstrakt: Heats of formation of rate-earth monosulfate complexes have been measured calorimetrically for the ions La3+, Sm3+, Tb3+, and Er3+, in D2O and H2O solvents. Within the limits of experimental error there is no evidence for a solvent isotope effect on the heat and entropy changes of these complexation reactions.
Databáze: Supplemental Index