| Autor: |
Tasker, Ian, Wood, Robert |
| Zdroj: |
Journal of Solution Chemistry; July 1982, Vol. 11 Issue: 7 p469-480, 12p |
| Abstrakt: |
Enthalpies of dilution of aqueous systems containing trioxane, and trioxane with each of mannitol, inositol and cyclohexanol have been determined at 25°C. The data have been treated in terms of the Savage-Wood additivity principle and, in conjunction with literature data on ether compounds a revised estimate of the pairwise group-interaction enthalpy for CH2/−O− and a first estimate for CHOH/−O− are presented. Systems of saccharides and saccharides with alcohols do not conform to the Savage-Wood principle and an explanation in terms of the specific hydration properties of saccharides is offered. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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