Copper(I) nitrate π-complexation: Synthesis and crystal structure of [(CH2=CH−CH2)2NH2][Cu(NO3)2] compound

Autor:	Olijnyk, Volodymyr, Głowiak, Tadeusz, Mys'kiv, Marian
Zdroj:	Journal of Chemical Crystallography; October 1995, Vol. 25 Issue: 10 p621-624, 4p
Abstrakt:	By means of alternating current electrochemical synthesis, triclinic crystals of [(C3H5)2NH2][Cu(NO3)2] p-complex were obtained: space group ,a=7.218(2),b=7.536(2),c=10.231 (3) Å, a=74.75(3), ß=82.47(3), ?.=77.22(3)°, andDmeas=1.80(1)g cm-3 forZ=2. The structure consists of diallylammonium cations which form two p-coordinate bonds to the same copper atom. Oxygen atoms from NO3-anions complete the trigonal pyramidal metal environment. The coordinated C=C bonds are lengthened to 1.349(5) and 1.369(5) Å.
Databáze:	Supplemental Index
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