Methanol conversion to hydrocarbons over H-ZSM-5: Further evidence for the role of NO

Autor: Hutchings, Graham J., Rensburg, Lawrence Jansen, Copperthwaite, Richard G., Hunter, Roger, Dwyer, John, Dewing, John
Zdroj: Catalysis Letters; January 1990, Vol. 4 Issue: 1 p7-14, 8p
Abstrakt: Inhibition of the methanol to gasoline reaction induced by co-feeding of nitric oxide is compared and contrasted with inhibition by ammonia. It is concluded that NO does not act as a catalyst poison by being converted to NH3. A mechanism for inhibition of the reaction by NO based on the Barton reaction is proposed.
Databáze: Supplemental Index