Novel iron meso-nitrooctaethylporphine complexes for the catalytic reaction of alkanes with molecular oxygen
Autor: | Ellis, P. E., Lyons, J. E., Shaikh, S. N. |
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Zdroj: | Catalysis Letters; March 1994, Vol. 24 Issue: 1-2 p79-83, 5p |
Abstrakt: | Introducing nitro groups into themeso-positions of a metalloporphyrin converts a catalytically inactive complex into a highly active catalyst for the oxidation of alkanes with molecular oxygen. The degree of nitration correlates with both the Fe(III)/Fe(II) reduction potential and the catalytic activity. |
Databáze: | Supplemental Index |
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