Novel iron meso-nitrooctaethylporphine complexes for the catalytic reaction of alkanes with molecular oxygen

Autor: Ellis, P. E., Lyons, J. E., Shaikh, S. N.
Zdroj: Catalysis Letters; March 1994, Vol. 24 Issue: 1-2 p79-83, 5p
Abstrakt: Introducing nitro groups into themeso-positions of a metalloporphyrin converts a catalytically inactive complex into a highly active catalyst for the oxidation of alkanes with molecular oxygen. The degree of nitration correlates with both the Fe(III)/Fe(II) reduction potential and the catalytic activity.
Databáze: Supplemental Index