Novel modified chiral NiII complexes with the Schiff bases of ( E )-and ( Z )-2-aminobut-2-enoic acids: Synthesis and study

Autor: Saghiyan, A., Manasyan, L., Dadayan, S., Petrosyan, S., Petrosyan, A., Maleev, V., Khrustalev, V.
Zdroj: Russian Chemical Bulletin; March 2006, Vol. 55 Issue: 3 p442-450, 9p
Abstrakt: Abstract: NiII complexes with the Schiff bases of (E)-and (Z)-2-aminobut-2-enoic acids were obtained with (S)-N-(2-benzoylphenyl)-1-(2-chlorobenzyl)pyrrolidine-2-carboxamide and (S)-N-(2-benzoylphenyl)-1-(3,4-dimethylbenzyl)pyrrolidine-2-carboxamide as new chiral auxiliaries. Asymmetric addition of nucleophiles to the C=C bond of these complexes was studied.
Databáze: Supplemental Index
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