Oxovanadium(IV) and Niobium(V) Complexes with Some New Schiff Bases

Autor: Shashidhara, G.M., Goudar, T.R.
Zdroj: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry; September 2000, Vol. 30 Issue: 8 p1581-1599, 19p
Abstrakt: AbstractComplexes of the type [VO(LH)(H2O)] and [Nb(LH)2Cl3], where LH = a singly deprotonated Schiff base derived from condensation of 3-substituted-4-amino-5-mercapto-l,2,4-triazole with benzoin were synthesized in ethanol or dry chloroform, respectively. A coordination number of five for the oxovanadium(IV) and seven for the niobium(V) complexes have been proposed on the basis of analytical, molar conductance, magnetic, IR and 1H NMR spectral data. Kinetic parameters were established by adopting Broido's method. All of the ligands and their oxovanadium(IV) complexes were screened for their antibacterial, antifungal and antituberculosis activity.
Databáze: Supplemental Index