Structure of products of H-H and C-H bond activation by Ni atom, Ni2cluster, and Ni-porphyrin complex of Ni2cluster

Autor: Mamaev, V. M., Gloriozov, I. P., Lemenovskii, D. A., Zernova, E. V.
Zdroj: Kinetics and Catalysis; January 2000, Vol. 41 Issue: 1 p33-37, 5p
Abstrakt: New catalytic systems based on porphyrin complexes of Ni2cluster and capable of activating C-H and H-H bonds are proposed. DFT calculations showed that a Ni2cluster can coordinate Ni-porphyrin with a considerable gain in energy. The structures of the products of methane and hydrogen activation were discussed.
Databáze: Supplemental Index