| Autor: |
Namme, Rie, Mitsugi, Takashi, Takahashi, Hideyo, Ikegami, Shiro |
| Zdroj: |
European Journal of Organic Chemistry; August 2007, Vol. 2007 Issue: 22 p3758-3764, 7p |
| Abstrakt: |
The stereoselective synthesis of ketoside-type analogues of trehalose is described. O-Glycosidation of hept-2-ulopyranose with trimethylsilyl α-pyranoside promoted by trimethylsilyl trifluoromethanesulfonate afforded α-ketopyranosyl α-aldopyranosides exclusively. α-Ketopyranosyl β-aldooyranosides and α-ketopyranosyl α-ketopyranosides were also synthesized in a similar manner. The benzyl protecting groups of the hydroxy moieties were removed by hydrogenolysis to afford fully deprotected trehalose analogues.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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