Radiolysis of aqueous solutions of nucleic acid fragments. Reactions of pyrimidyl radicals with alcohol

Autor: Fel, N. S., Zaozerskaya, L. A., Dolin, P. I.
Zdroj: Radiation Effects and Defects in Solids; July 1972, Vol. 15 Issue: 1 p57-59, 3p
Abstrakt: Using a steady state concentration method we have measured the rate constants of reactions of radicals, formed upon addition of OH and eaq to pyrimidine base thymine (T) - (T+OH)=R1 and (T+e-aq)=R2 with methanol. We find K=(0.8±0.2).104 M-1 sec-1 and K > 2,3.103 M-1 sec-1 respectively.
Databáze: Supplemental Index