SECONDARY EFFECTS ASSOCIATED WITH THE FUNCTIONING OF BULKY SUBSTITUTED AMMONIUM CATIONS - REVISED INTERPRETATIONS.

Autor: Preez, J.G.H. du, Shillington, DP., Herselman, E., Rohwer, H. E., van Brecht, B. J. A. M., Wilke, H.
Zdroj: Solvent Extraction and Ion Exchange; March 1995, Vol. 13 Issue: 2 p189-214, 26p
Abstrakt: The behaviour of mono and diquaternary ammonium cations during extraction and precipitation of CoCI4 2 ions is used to clarify some aspects of the secondary effects present during their operation. A quantitative treatment of the "HCI effect" is offered. It is illustrated that this effect must be ascribed to a lowering of the activity of the cation rather than formation of undissociated acid species like H2CoCI4
Databáze: Supplemental Index