A NOVEL METHOD OF SULFIDE SYNTHESIS FROM SULFOXIDES WITH N,N-DIMETHYLTHIOFORMAMIDE

Autor: Kamijo, Haruo, Takido, Toshio, Nakazawa, Toshikatsu, Itabashi, Kunio, Seno, Manabu
Zdroj: Phosphorus, Sulfur, and Silicon and the Related Elements; January 1993, Vol. 82 Issue: 1 p207-210, 4p
Abstrakt: Sulfoxides were deoxygenated by N,N-dimethylthioformamide (DMTF) to give quantitatively the corresponding sulfides in the presence of the catalytic amount of sulfuric acid under mild conditions. DMTF changes into dimethylformamide (DMF) by this reaction and it may be used in a recycling way. since DMF is converted into DMTF by diphosphorus pentasulfide in a good yield.
Databáze: Supplemental Index