| Autor: |
Zaremski, M. Yu., Chernikova, E. V., Izmailov, L. G., Garina, E. S., Olenin, A. V. |
| Zdroj: |
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry; April 1996, Vol. 33 Issue: 4 p237-242, 6p |
| Abstrakt: |
The free radical polymerization of styrene initiated by inifener (Sbenzyldithiocarbamate groups introduced onto Silochrome surface) is studied under ultra-violet irradiation. It is revealed that the type of chemical binding of iniferter groups with the silica surface affects drastically the mechanism of polymerization. A living graft polymerization is suggested in case of chemical grafting of S-benzyl-groups onto the surface, while non-living free-radical polymerization proceeds in case of grafting of dithiocarbamate groups. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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