Autor: |
Sarathy, T. Partha, Srinivas, P., Rao, K. Nageswar, Sethuram, B., Rao, T. Navaneeth |
Zdroj: |
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry; September 1989, Vol. 26 Issue: 9 p1347-1353, 7p |
Abstrakt: |
A new photoinitiating system (eosin-periodate) was employed for the polymerization of acrylonitrile in which dye acts as both sensitizer and reducing agent. The rate of polymerization was found to be proportional to monomer concentration, dye concentration, and light intensity, but independent of periodate concentration. A mechanism involving initiation by OH radicals and termination by periodate is proposed to explain the results. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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