| Autor: |
Thomlinson, M. M., Outhwaite, C. W. |
| Zdroj: |
Molecular Physics; December 1982, Vol. 47 Issue: 5 p1113-1128, 16p |
| Abstrakt: |
A modified Poisson-Boltzmann equation is derived for a single primitive model electrolyte with unequal ion sizes. Charge oscillations are found which are similar to those found in the restricted primitive model, but which occur at a higher concentration. Calculations for a 1:1 electrolyte are in reasonable agreement with HNC calculations. There is an inconsistency in the anion-cation radial distribution function which can be serious at high concentrations or high electrolyte valencies. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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