Efficient Metallo−Ene Reactions in Organoaqueous Phase

Autor: Michelet, V., Galland, J.-C., Charruault, L., Savignac, M., Genet, J.-P.
Zdroj: Organic Letters; June 2001, Vol. 3 Issue: 13 p2065-2067, 3p
Abstrakt: The easily prepared catalyst systems PdCl2, RhCl2(COD)2, NiCl2·6H2O, or Ni(COD)2/TPPTS have been found to form a C−C bond in organoaqueous medium. Intramolecular metallo−ene reactions have been efficiently realized. Metal selectivity has been discovered.
Databáze: Supplemental Index