Asymmetric Intramolecular C−H Insertions of Aryldiazoacetates

Autor: Davies, H. M. L., Grazini, M. V. A., Aouad, E.
Zdroj: Organic Letters; May 2001, Vol. 3 Issue: 10 p1475-1477, 3p
Abstrakt: The enantioselectivity of Rh2(S-DOSP)4 catalyzed C−H insertion of aryldiazoacetates is very dependent on the site of the C−H insertion. The highest enantioselectivity is obtained for insertion into methine C−H bonds.
Databáze: Supplemental Index