Autor: |
Couturier, M., Tucker, J. L., Andresen, B. M., Dube, P., Negri, J. T. |
Zdroj: |
Organic Letters; February 2001, Vol. 3 Issue: 3 p465-467, 3p |
Abstrakt: |
Palladium and Raney nickel were found to catalyze the methanolysis of borane−amine adducts. Hence, strongly complexed amines can now be liberated by simple treatment with Pd/C or Raney Ni in methanol. The method is applicable to primary, secondary, tertiary, and aromatic amines, and the mildness of the reaction conditions allows preservation of otherwise labile functional groups. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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