| Autor: |
Foti, C. J., Fields, J. D., Kropp, P. J. |
| Zdroj: |
Organic Letters; September 1999, Vol. 1 Issue: 6 p903-904, 2p |
| Abstrakt: |
Some solid reagents traditionally supported on silica gel or alumina are also effective as heterogeneous reactants in the absence of a support. Moist magnesium monoperoxyphthalate (MMPP), either suspended in CH2Cl2 or solventless, is a convenient alternative to peroxycarboxylic acids for oxidation of sulfides and epoxidation of alkenes. The latter reaction exhibits an unusual order of reactivity: trisubstituted > disubstituted > tetrasubstituted. Unsupported moist Ca(OCl)2 and OXONE are also effective oxidants. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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