Simple Primary Anilines as Iminium Catalysts for the Epoxidation of α-Substituted Acroleins

Autor: Erkkilä, Anniina, Pihko, Petri 4;M., Clarke, Melanie-Rose
Zdroj: Advanced Synthesis & Catalysis; April 2007, Vol. 349 Issue: 6 p802-806, 5p
Abstrakt: Simple ortho-alkylated anilines have been shown to be excellent iminium catalysts for the epoxidation reaction of α-substituted acroleins. A range of different α-substituted acroleins give the epoxide products in good to excellent yields and good chemoselectivity.
Databáze: Supplemental Index