Novel Base-Catalyzed Rearrangement of the Taxane Skeleton1

Autor: Appendino, G., Fenoglio, I., Velde, D. G. Vander
Zdroj: Journal of Natural Products; May 22, 1997, Vol. 60 Issue: 5 p464-466, 3p
Abstrakt: Methanolysis of taxicin I esters afforded the 1,15-secotaxane 4, the result of a vinylogous retro-aldol reaction followed by acetalization and a transannular hydride shift.
Databáze: Supplemental Index