Transition-Metal-Catalyzed Imine Metathesis

Autor: Cantrell, G. K., Meyer, T. Y.
Zdroj: Organometallics; December 9, 1997, Vol. 16 Issue: 25 p5381-5383, 3p
Abstrakt: Mixtures of (n-Pr)N&dbd;CHPh (3) and PhN&dbd;CH(t-Bu) (4) undergo catalytic metathesis in the presence of 4 mol % of (DME)Cl2Mo(&dbd;NR)2 (R = t-Bu (1a), 2,6-diisopropylphenyl (2)) at 85−90 °C in C6D6 to form 1:1:1:1 equilibrium mixtures with PhN&dbd;CHPh (5) and (n-Pr)N&dbd;CH(t-Bu) (6).
Databáze: Supplemental Index