Chiroptical Molecular Switches 1; Principles and Syntheses

Autor: De Lange, Ben, Sager, Volter, Feringa, Ben
Zdroj: Molecular Crystals and Liquid Crystals; June 1992, Vol. 217 Issue: 1 p129-132, 4p
Abstrakt: The concept and the synthesis of the basic molecules for a chiroptical molecular switch are described. This molecular switch is based on photochemical interconversion of two bistable forms of chiral sterically overcrowded olefins. A large variety of these alkenes with different properties have been prepared by the use of a coupling reaction between a thioketone and a diazo compound.
Databáze: Supplemental Index