Autor: |
Morawski, P., Gramza, M., Goslar, J., Hilczer, W., Szczepanska, L., Hoffmann, S. K. |
Zdroj: |
Ferroelectrics Letters Section; March 1998, Vol. 23 Issue: 5 p121-126, 6p |
Abstrakt: |
EPR of γ-ray generated PO32- radicals indicates that the four radical centers are equivalent in the paraelectric phase and become inequivalent in the ferroelectric phase due to a ±3° rotation. The phase transition temperature is shifted by irradiation from Tc = 224 K to Tc = 180 K. The molecular mechanism of the order-disorder phase transition is discussed |
Databáze: |
Supplemental Index |
Externí odkaz: |
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