A reorientation of the PO3-groups and radiation damage effect in ferroelectric phase transition studied by CW-EPR of PO32- radical in glycine·H3PO3 single crystal

Autor: Morawski, P., Gramza, M., Goslar, J., Hilczer, W., Szczepanska, L., Hoffmann, S. K.
Zdroj: Ferroelectrics Letters Section; March 1998, Vol. 23 Issue: 5 p121-126, 6p
Abstrakt: EPR of γ-ray generated PO32- radicals indicates that the four radical centers are equivalent in the paraelectric phase and become inequivalent in the ferroelectric phase due to a ±3° rotation. The phase transition temperature is shifted by irradiation from Tc = 224 K to Tc = 180 K. The molecular mechanism of the order-disorder phase transition is discussed
Databáze: Supplemental Index