| Autor: |
et, M. Rivière-Baudet, Satgè, J. |
| Zdroj: |
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry; January 1971, Vol. 1 Issue: 4 p257-264, 8p |
| Abstrakt: |
(trialkylgermyl) dialkylamines react with γ-butyrolactone and diacid anhydrides giving acyl-oxygen bond cleavage and insertion which lead to the corresponding amid-alkoxygermanes or germanium ester-amides.Structures of these derivatives were established by IR and NMR spectroscopy and by identification of their hydrolysis products.The same germylamines react with vinylacetate, by acyl-oxygen bond cleavage to form vinyloxygermanes in good yields. With isopropenyl acetate, isopropenyloxygermane is not the only derivative formed, we have also observed a low proportion of NMe2/CH3 COO substitution. The germanotropic equilibrium of isopropenyloxygermane - germylacetone is observed. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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