Selective Determination of Organic and Inorganic Thiocyanates in Aqueous Solution by IR Spectrophotometry

Autor: Liberatori, A., La Noce, T., Loreti, L., Pettine, M.
Zdroj: International Journal of Environmental & Analytical Chemistry; October 1985, Vol. 22 Issue: 1 p109-114, 6p
Abstrakt: A new spectrophotometric method for the determination in aqueous solution of both organic and inorganic thiocyanates is described. Organic thiocyanates are determined by measuring at wavenumber of 2150 cm-1 the absorption of solutions directly extracted with carbon tetrachloride. Inorganic thiocyanates require a previous derivatization reaction with dimethylsulfate, and are determined as methylthiocyanates. The method is quick, accurate and selective. The results obtained suggest its utilization in analysis of aqueous samples.
Databáze: Supplemental Index