A New Furan Synthesis. Evidence for the Intermediacy of the Elusive Anhydro-5-hydroxy-1,3-dioxolium Hydroxide System

Autor: Berk, Howard, Zwikelmaier, Kurt, Franz, John
Zdroj: Synthetic Communications; January 1980, Vol. 10 Issue: 9 p707-710, 4p
Abstrakt: While five-membered mesoionic ring systems have been employed as useful synthetic intermediates in the preparation of a wide variety of pyrroles and thiophenes1, only limited application has been made to the preparation of furans2. We would like to report a new furan synthesis in which the unreported anhydro-5-hydroxy-1, 3-dioxolium hydroxide system may be an intermediate.
Databáze: Supplemental Index