| Autor: |
Serrar, C., Ouassas, A., Boutalib, A., Frange, B. |
| Zdroj: |
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry; April 1996, Vol. 26 Issue: 4 p669-683, 15p |
| Abstrakt: |
Octahydrotriborate salts, B3H8-, have been prepared by the reaction of NaBH4 with Lewis acids such as BX3·BDMA (BDMA = benzyldimethylamine, × = Cl,Br) or C2H5I in diglyme. The presence of BH3·BDMA as a by-product in the former reaction provides new insight into the reaction mechanism of B11H14- formation. In acetonitrile-water solutions of HCl or CH3CO2H, the B3H8- anion reacted to give B3H7CH3CN or B3H7CH3CO2- characterized by 11B NMR spectroscopy. Their kinetic hydrolysis study was consistent with NMR analysis. Reaction of Bu4NB3H8 and CuCl2 at 0°C produced pure B3H6Cl2-. An AM1 theoretical study of the substituted derivatives B3H7L (L = Cl-, CH3CN, CH3CO2-, OH-) and B3H6L2 (L = Cl-) is reported. |
| Databáze: |
Supplemental Index |
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