| Autor: |
Oxley, J. C., Smith, J. L., Rogers, E., Dong, X. X. |
| Zdroj: |
The Journal of Physical Chemistry - Part A; May 8, 1997, Vol. 101 Issue: 19 p3531-3536, 6p |
| Abstrakt: |
Isotopically labeled 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO) was used to determine the origins of nitrogen atoms in its decomposition gases. NTO samples with 15N labels at 1 and 2 positions, the 4 position, and the 6 position of NTO were synthesized.1 The thermolysis of NTO yields a brown insoluble residue and the nitrogen-containing gases dinitrogen, nitrous oxide, nitric oxide, and hydrogen cyanide. The analysis of these nitrogen-containing gases is reported, and the mechanistic implications are considered. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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