Spectrofluorimetric Determination of Zirconium Based on the Inclusion Complex of 8-Hydroxy 7 Iodo Quinoline Sulfonic Acid with -Cyclodextrin As Ligand

Autor: Sánchez, Francisco García, Gómez, José Carlos Márquez, López, Miguel Hernandez
Zdroj: Analytical Letters; May 1990, Vol. 23 Issue: 5 p923-933, 11p
Abstrakt: Ferron form inclusion complex with -cyclodextrin in aqueous media at pH 3.2 with an association constant of 25 M-1. This ligand has been used for the fluorimetric determination of zirconium at trace levels. The limit of detection is 0.07 g/ml and the RSD is 5.2%. A significant improvement in selectivity is gained in the -CD method compared to the method in absence of cyclodextrin.
Databáze: Supplemental Index