Exploitation of the photochromic nitroprusside anion [ FeNO(CN)5] 2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

Autor: Shibaeva, R., Khasanov, S., Zorina, L., Simonov, S., Shevyakova, I., Kushch, L., Buravov, L., Yagubskii, E., Baudron, S., Mézière, C., Batail, P., Canadell, E., Yamada, J., Shibaeva, R., Khasanov, S., Zorina, L., Simonov, S., Shevyakova, I., Kushch, L., Buravov, L., Yagubskii, E., Baudron, S., Mézière, C., Batail, P., Canadell, E., Yamada, J.
Zdroj: Journal de Physique IV - Proceedings; April 2004, Vol. 114 Issue: 1 p481-485, 5p
Abstrakt: The radical cation salts based on BDH-TTP and the mono- and diamide functionalized derivatives of EDT-TTF with the double charged nitroprusside anion [ FeNO(CN)5] 2- (NP): $\kappa $-(BDH-TTP)4[NP]C6H5NO2(1), $\kappa $-(BDH-TTP)4[NP] (2), (BDH-TTP)2[NP] (3), α-[ EDT-TTF-CONH2] 4[NP] (4), $\beta $-[ EDT-TTF-(CONH$_{2})_{2}$] 2[NP]0.5(C6H5NO$_{2})_{0.5}$(5) have been synthesized. The crystal structures and transport properties of 1 –5, as well as electronic band structures of 1and2have been studied. Key words.organic conductors based on radical cation salts – X-ray and band structure – conductivity.
Databáze: Supplemental Index