Synthesis and magnetic studies of the ${\pi }$-d ferrimagnet TTF[ Cr(NCS)${_{4}}$(1,10'-phenanthroline)] , TTF = tetrathiafulvalene

Autor: Turner, S. S., Carling, S. G., Day, P., Gómez-Garcia, C. J., Coronado, E., Turner, S. S., Carling, S. G., Day, P., Gómez-Garcia, C. J., Coronado, E.
Zdroj: Journal de Physique IV - Proceedings; April 2004, Vol. 114 Issue: 1 p585-587, 3p
Abstrakt: A new synthesis route to the $\pi $-d ferrimagnet TTF[ Cr(NCS)4(1,10'-phenanthroline)] is described along with recent magnetic investigations. In particular the variable frequency AC magnetisation of the protonated and fully deuterated samples indicate no frequency dependence and a Tcof 8.7 K. Single crystal heat capacity and muon spin relaxation experiments show a second magnetic transition at 2.4 K. Key words.Charge-transfer salts, conductivity, ferrimagnetism.
Databáze: Supplemental Index