Partial Oxidation of Methanol on a Sn−Mo−O Catalyst. A Kinetic Study

Autor: Ardissone, D. E., Valente, N. G., Cadus, L. E., Arrua, L. A.
Zdroj: Industrial & Engineering Chemistry Research; August 7, 2000, Vol. 39 Issue: 8 p2902-2909, 8p
Abstrakt: A Sn−Mo−O catalyst was prepared, characterized, and tested in the partial oxidation of methanol under different experimental conditions. A kinetic model which assumes that the reaction involves different active sites such as terminal and bridged oxygen vacancy sites, terminal oxygen (Mo&dbd;O), and dual dioxo sites (two adjacent surface dioxo units) has been selected. The experimental observations and the predictions of the model show a rather good agreement.
Databáze: Supplemental Index