| Autor: |
Schmidt-Winkel, P., Lukens, W. W., Jr., Yang, P., Margolese, D. I., Lettow, J. S., Ying, J. Y., Stucky, G. D. |
| Zdroj: |
Chemistry of Materials; March 20, 2000, Vol. 12 Issue: 3 p686-696, 11p |
| Abstrakt: |
Siliceous mesostructured cellular foams (MCFs) with well-defined ultralarge mesopores and hydrothermally robust frameworks are described. The MCFs are templated by oil-in-water microemulsions and are characterized by small-angle X-ray scattering, nitrogen sorption, transmission electron microscopy, scanning electron microscopy, thermogravimetry, and differential thermal analysis. The MCFs consist of uniform spherical cells measuring 24−42 nm in diameter, possess BET surface areas up to 1000 m2/g and porosities of 80−84%, and give, because of their pores with small size distributions, higher-order scattering peaks even in the absence of long-range order. Windows with diameters of 9−22 nm and narrow size distribution interconnect the cells. The pore size can be controlled by adjusting the amount of the organic swelling agent that is added and by varying the aging temperature. Adding ammonium fluoride selectively enlarges the windows by 50−80%. In addition, the windows can be enlarged by postsynthesis treatment in hot water. The MCF materials resemble aerogels, but offer the benefits of a facilitated synthesis in combination with well-defined pore and wall structure, thick walls, and high hydrothermal stability. The open system of large pores give MCFs unique advantages as catalyst supports and separation media for processes involving large molecules, and the high porosities make them of interest for electrical and thermal insulation applications. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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