| Autor: |
Tret'yakov, V. P., Rudakov, E. S., Min'ko, L. A., Zimtseva, G. P. |
| Zdroj: |
Theoretical and Experimental Chemistry; July 2000, Vol. 36 Issue: 4 p224-227, 4p |
| Abstrakt: |
A new variant of the kinetic distributive method was used to study the kinetics of the oxidation of ethylene by PdCl2complexes supported on silica gel taking account of the equilibrium distribution of ethylene between the gas phase, silica gel, and metal complex reaction sites. Mono-, bi-, and polynuclear palladium(II) species are found to participate in the reaction. The PdIIactivity increases with increasing amount of nuclei in the species. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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