Highly Diastereoselective Preparation of anti-1,2-Diols by Catalytic Addition of Alkynylsilanes to -Silyloxyaldehydes
| Autor: | Sa-ei, Kanicha, Montgomery, John |
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| Zdroj: | Organic Letters; September 2006, Vol. 8 Issue: 20 p4441-4443, 3p |
| Abstrakt: | The catalytic, diastereoselective coupling of -silyloxy aldehydes and alkynylsilanes catalyzed by a nickel(0) N-heterocyclic carbene complex provides an effective entry to anti-1,2-diols. The scope of couplings and extent of diastereoselection are excellent across a range of substrates. |
| Databáze: | Supplemental Index |
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