Solubilization and Titania Nano-Coating of Carbon Nanotubes Using Titanium (IV) Tetrabutoxide.

Autor: Daisuke SAKEMI, Wataru FUTAGAMI, Yoshitaka KUDO, Shinya ONOUE, Seung-Woo LEE, Toyoki KUNITAKE
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Zdroj: Kobunshi Ronbunshu; 2013, Vol. 70 Issue 6, p253-261, 9p
Abstrakt: Single-walled and multi-walled carbon nanotubes (CNTs) are soluble in toluene containing titanium (IV) tetrabutoxide and their surface could be successfully covered with an ultrathin TiO2 layer. AFM, SEM, TEM, XPS, X-ray and TG-DTA analysis indicate the TiO2 coating on the surface of CNTs through the hydrolysis of bound titanium alkoxid molecules. After calcination at 450-550°C, the SWNTs were completely decomposed from the composites and crystalline TiO2 nanotubes that reflect the shape of the SWNTs were formed. From the XPS results of the prepared TiO2/MWNTs samples, the atomic ratio of Ti to C is circa 1:100, indicating that the coated TiO2 layer is very thin. The current approach provides a new direction for hybridization of CNTs with TiO2 that is photocatalytically active in TiO2/CNTs nanocomposites. [ABSTRACT FROM AUTHOR]
Databáze: Supplemental Index