A Notable Difference in Photoluminescent Efficiency between a Newly Synthesized Asymmetric Dinuclear Cu(I) Cyano Complex Building Unit [Cu2(CN)5]3- and a Symmetric Unit [Cu2(CN)6]4-.

Autor:	Fuchiwaki, Junta, Shin-ichi Nishikiori
Předmět:	COORDINATION polymers PHOTOLUMINESCENCE COPPER compounds POLYMERS CADMIUM compounds
Zdroj:	Chemistry Letters; 6/5/2010, Vol. 39 Issue 6, p28-28, 1p
Abstrakt:	A new cyano-bridged Cu(I)/Cd(II) coordination polymer K[CdCu2(CN)5]·dce·3H2O (dce = 1,2-dicyanoethane) containing a novel asymmetric dinuclear Cu(I) building unit [Cu2(CN)5]3- was synthesized, and its emission intensity was very weak in contrast to very strong emission of CdCu (CN)3·hpn·2H2O (hpn = 3-hydroxypropionitrile) containing an already known symmetric building unit [Cu2(CN)6]4-. [ABSTRACT FROM AUTHOR]
Databáze:	Supplemental Index
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