Synthetic Applications of Tandem Reaction Sequences Involving Hydroformylation.

Autor: Beller, Matthias, Eilbracht, Peter, Schmidt, Axel M.
Zdroj: Catalytic Carbonylation Reactions; 2006, p65-95, 31p
Abstrakt: Aldehydes obtained from olefins under hydroformylation conditions can be converted to more complex reaction products in one-pot reaction sequences. These involve heterofunctionalization of aldehydes to form acetals, aminals, imines and enamines, including reduction products of the latter in an overall hydroaminomethylation. Furthermore, numerous conversions of oxo aldehydes with additional C,C-bond formation are conceivable such as aldol reactions, allylations, carbonyl olefinations, ene reactions and electrophilic aromatic substitutions, including Fischer indole syntheses. [ABSTRACT FROM AUTHOR]
Databáze: Supplemental Index