| Autor: |
Davison, A., Dewar, M. J. S., Hafner, K., Heilbronner, E., Hofmann, U., Niedenzu, K., Schäfer, Kl., Wittig, G., Boschke, F., Cram, D. J., Cram, J. M., Pullman, A., Freed, K. F., Freed, Karl F. |
| Zdroj: |
Stereo- & Theoretical Chemistry; 1972, p105-139, 35p |
| Abstrakt: |
A unified fully quantum mechanical description of all of the diverse radiationless phenomena has been presented. This provides an understanding of the dissipative and nondissipative aspects associated with radiationless processes in small, large, and intermediate case molecules. The full rate expression is analyzed to provide the observed energy gap law and the associated isotope effects. The theory is generalized to treat nonradiative decay rates in dense media and to evaluate the dependence of these rates on particular selected vibronic states. The relevance of this theory to the study of photochemical processes is also noted. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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