Autor: |
Matsui, Hideo, Kawahara, Tetsuro, Mishima, Masaru, Yoshihara, Masakuni |
Předmět: |
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Zdroj: |
Polymer Journal; 2005, Vol. 37 Issue 9, p656-660, 5p, 6 Diagrams, 3 Charts, 3 Graphs |
Abstrakt: |
A ternary, scandium-phenylene-yttrium hybrid copolymer was synthesized by initially reacting 1,4-hydroquinone with scandium isopropoxide below -45 °C followed by a second reaction with yttrium isopropoxide at room temperature. ESR spectral examinations and ab-initio calculations indicate that an electron transfer takes place initially from the phenylene group to the yttrium atom at a lower energy-level and then to the scandium atom at a higher energy-level, i.e. via two-step electron transportation. [ABSTRACT FROM AUTHOR] |
Databáze: |
Supplemental Index |
Externí odkaz: |
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