Synthesis and Electronic Behavior of a Net-Worked Scandium-Phenylene-Yttrium Ternary Hybrid Copolymer.

Autor: Matsui, Hideo, Kawahara, Tetsuro, Mishima, Masaru, Yoshihara, Masakuni
Předmět:
Zdroj: Polymer Journal; 2005, Vol. 37 Issue 9, p656-660, 5p, 6 Diagrams, 3 Charts, 3 Graphs
Abstrakt: A ternary, scandium-phenylene-yttrium hybrid copolymer was synthesized by initially reacting 1,4-hydroquinone with scandium isopropoxide below -45 °C followed by a second reaction with yttrium isopropoxide at room temperature. ESR spectral examinations and ab-initio calculations indicate that an electron transfer takes place initially from the phenylene group to the yttrium atom at a lower energy-level and then to the scandium atom at a higher energy-level, i.e. via two-step electron transportation. [ABSTRACT FROM AUTHOR]
Databáze: Supplemental Index