Relationships between radionuclides, metals, and sediment properties in sediment of a bay exposed to anthropogenic pressure and mixed sediment sources (Kaštela Bay, Adriatic Sea, Croatia).

Autor: Lovrenčić Mikelić, Ivanka, Oreščanin, Višnja, Cukrov, Neven, Tomašić, Nenad, Rubčić, Mirta, Barišić, Delko
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Zdroj: Marine Pollution Bulletin; Dec2023, Vol. 197, pN.PAG-N.PAG, 1p
Abstrakt: Natural and anthropogenic radionuclides, metals, organic matter, sediment grain size, mineral composition, and sediment sources were studied in marine sediment of Kaštela Bay up to a depth of 0.5 m. Deposition of man-modified material into the sea was evidenced in sediment mineral composition. Presence of pyrite and hematite in this sediment may pose an environmental concern. Metals, radionuclides, and organic matter were grouped in three groups: (i) variables under no anthropogenic influence and preferentially associated with carbonates (Ca, Sr); (ii) variables under no or weak anthropogenic influence and preferentially associated with aluminosilicates (Al, K, Ti, V, Cr, Mn, Fe, Co, Ni, Ga, Rb, Y, 40K, 232Th); (iii) variables under notable anthropogenic influence and/or natural processes of separation (Cu, Zn, Pb, As, 226Ra, 238U, 137Cs, organic matter). Predominant influencing parameters change with sediment depth for some variables. Anthropogenic influence was the most emphasised for Cu, Zn, and Pb, followed by 137Cs. • Predominant influencing parameters vary with sediment depth. • Significant anthropogenic impact on Cu, Zn, Pb, and 137Cs • 137Cs introduction path into environment not differentiated • 226Ra and 238U possibly separated by natural processes. • Mineral composition reveals fly and bottom ash deposition in the sea. [ABSTRACT FROM AUTHOR]
Databáze: Supplemental Index