Experimental insights on the synthesis and characteristics of Fe1−xBixVO4 photocatalysts for efficient environmental and electrical applications.

Autor: Munir Sajid, Muhammad, Zhai, Haifa, Iqbal, Muhammad Aamir, Akhtar Shad, Naveed, Javed, Yasir, Raza Ishaq, Ali, Abd Alreda, Baraa, Morsy, Kareem, Choi, Jeong Ryeol
Zdroj: Arabian Journal of Chemistry; Aug2023, Vol. 16 Issue 8, pN.PAG-N.PAG, 1p
Abstrakt: In this study, polycrystalline Fe 1−x Bi x VO 4 (0.0 ≤ x ≤ 1.0) photocatalysts were synthesized hydrothermally. The as-produced photocatalysts' morphology, crystal structure, chemical content, optical bandgap energy, electrochemical behavior, and interfacial characteristics were measured using the XRD, SEM, EDX, FTIR, XPS, UV–Vis-DRS, BET, and PL characterizations. The photocatalysis investigations were conducted to see whether the poisonous crystal violet (CV) dye could be decomposed over the Fe 1−x Bi x VO 4 composite. The surface plasmon resonance (SPR) nature of Bi3+ can markedly raise the level of sensitivity to visible light, which would enhance the photocatalytic activity. By raising the electron population in Fe 1−x Bi x VO 4 , the Schottky barrier that SPR produces at the interface between Bi3+ and FeVO 4 increases the separation effectiveness of photoinduced charges. Various factors affecting the photocatalytic degradation of CV dye were examined in order to optimize the parameters. According to a radical trapping experiment, superoxide (O 2 ¯) radicals are the most active species in the degradation of the anionic CV dye. In comparison to FeVO 4 and BiVO 4 , these findings indicate that the Fe 1−x Bi x VO 4 composite possesses excellent photocatalytic and antibacterial activities. This work presents a novel approach to boosting light absorption, which encourages the development of effective photocatalysts for real-world uses. To observe the potential for additional applications, the antimicrobial and electrical properties of Fe 1−x Bi x VO 4 composites were also studied, and they exhibited good antimicrobial as well as electrical responses. [ABSTRACT FROM AUTHOR]
Databáze: Supplemental Index