| Autor: |
Jumpei Taguchi, Kota Kimura, Kazunobu Igawa, Katsuhiko Tomooka, Takamitsu Hosoya |
| Zdroj: |
Chemistry Letters; Feb2022, Vol. 51 Issue 2, p94-98, 5p |
| Abstrakt: |
The generation of 3-azidoarynes from o-iodoaryl triflatetype precursors was achieved using a silylmethyl Grignard reagent as the activator. The azido group served to control the regioselectivity of the reaction of 3-azidoarynes with arynophiles. The remaining azido group in the adduct also served as a transformable functional group, enabling further derivatization to various nitrogen-containing compounds. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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